Issue 18, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[RuVI(6,6′-Cl2bpy)2O2]2+(6,6′-Cl2bpy = 6,6′-dichloro-2,2′-bipyridine)

Chi-Ming Che  and  Wai-Ho Leung  

Abstract

Oxidation of cis-[RuII(6,6′-Cl2bpy)2(OH2)2]2+ with CeIV gave cis-[RuVI(6,6′-Cl2bpy)2O2]2+, isolated as the diamagnetic ClO4– salt, which rapidly oxidizes Cl–(to Cl2) and a wide variety of organic substrates (tetrahydrofuran to butyrolactone and cyclohexane to cyclohexanone).

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Article information

DOI
https://doi.org/10.1039/C39870001376
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1376-1377

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A cis-dioxoruthenium(VI) complex as active oxidant of chloride and organic substrates; preparation, characterization, and reactivity of cis-[RuVI(6,6′-Cl2bpy)2O2]2+(6,6′-Cl2bpy = 6,6′-dichloro-2,2′-bipyridine)

C. Che and W. Leung, J. Chem. Soc., Chem. Commun., 1987, 1376 DOI: 10.1039/C39870001376

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