Issue 19, 1987

Molybdenum hexadimethylamide

Abstract

The reaction between Mo(NMe2)4 and dry O2(ca. 0.5 equiv.) leads to Mo(NMe2)6 as an isolable amido compound (ca. 30% based on Mo); the Mo(NC2)6 unit has Th symmetry with Mo–N 2.034(1)Å, N–C 1.462(2)Å, and Mo–N–C 126.0(1)°.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1423-1424

Molybdenum hexadimethylamide

M. H. Chisholm, C. E. Hammond and J. C. Huffman, J. Chem. Soc., Chem. Commun., 1987, 1423 DOI: 10.1039/C39870001423

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