The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2l) with AgBF4 in Et2O has been shown to give a ca. 2 : 3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiMe2F)(SiEt2Ph); the reaction is thought to proceed via a Ph-bridged cation (II).
C. Eaborn, P. D. Lickiss, S. T. Najim and W. A. Stańczyk, J. Chem. Soc., Chem. Commun., 1987, 1461 DOI: 10.1039/C39870001461
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