Issue 20, 1987

Pentaco-ordinate silicon compounds in synthesis: regiospecific allylation of aldehydes by use of triethylammonium bis(pyrocatecholato)allylsilicates

Abstract

The title compounds, readily prepared from allytrimethoxysilane, pyrocatechol, and triethylamine, react with aldehydes regiospecifically and chemoselectively without catalyst under mild conditions: the allylation takes place even in protic solvents such as ethanol.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1517-1518

Pentaco-ordinate silicon compounds in synthesis: regiospecific allylation of aldehydes by use of triethylammonium bis(pyrocatecholato)allylsilicates

A. Hosomi, S. Kohra and Y. Tominaga, J. Chem. Soc., Chem. Commun., 1987, 1517 DOI: 10.1039/C39870001517

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