Issue 22, 1987

Photochemical epoxidation of alkenes by visible light in a redox system involving tetraphenylporphyrinantimony(V) and water

Abstract

Irradiation with visible light of a mixture of an alkene in degassed aqueous acetonitrile containing tetraphenylporphyrinantimony(V) as a sensitizer, methylviologen as an electron acceptor, and hydroxide ion, induced epoxidation of the alkene accompanied by hydrogen evolution, with water acting as the electron donor.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1681-1682

Photochemical epoxidation of alkenes by visible light in a redox system involving tetraphenylporphyrinantimony(V) and water

H. Inoue, M. Sumitani, A. Sekita and M. Hida, J. Chem. Soc., Chem. Commun., 1987, 1681 DOI: 10.1039/C39870001681

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