Issue 3, 1988

Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag6Cu7 cluster

Abstract

A novel silver–copper anionic cluster [Ag6Cu7(C2Ph)14] has been synthesized from the reaction of [PhC2AgC2Ph] and a mixture of [AgC2Ph]n and [CuC2Ph]n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu–Ag interactions to three tetranuclear [Ag2Cu2(C2Ph)4] subclusters, and within each unit of the sub-cluster, copper and silver atoms are bonded through metal–metal interactions and via bridged phenylethynyl ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 212-213

Preparation, identification, and X-ray structure of a novel high-nuclearity heterometallic anionic Ag6Cu7 cluster

O. M. Abu-Salah, M. S. Hussain and E. O. Schlemper, J. Chem. Soc., Chem. Commun., 1988, 212 DOI: 10.1039/C39880000212

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