Irradiation of N-hydroxy-2-thiopyridone esters of suitable γ,δ-unsaturated carboxylic acids in the presence of an electron deficient alkene produces complex bicyclic systems by a multiple radical addition chain mechanism.
D. H. R. Barton, E. da Silva and S. Z. Zard, J. Chem. Soc., Chem. Commun., 1988, 285 DOI: 10.1039/C39880000285
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