Issue 6, 1988

A [MnIII2O(MeCO2)2(H2O)2(bipy)2]2+(bipy = 2,2′-bipyridine) unit with accessible co-ordination sites. Contribution to the modelling of the photosynthetic oxygen evolving centre

Abstract

A new MnIII binuclear system with an oxo-bis(acetato) bridge and water co-ordinated to the Mn ions has been synthesized, crystallographically characterized, and its antiferromagnetic coupling measured (singlet–triplet gap 6·8 cm–1).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 431-432

A [MnIII2O(MeCO2)2(H2O)2(bipy)2]2+(bipy = 2,2′-bipyridine) unit with accessible co-ordination sites. Contribution to the modelling of the photosynthetic oxygen evolving centre

S. Ménage, J. Girerd and A. Gleizes, J. Chem. Soc., Chem. Commun., 1988, 431 DOI: 10.1039/C39880000431

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