Issue 6, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

The direct electrochemical synthesis of metal–diphenylphosphido complexes, and the crystal structure of Cu4(µ-PPh2)4(Ph2PCH2PPh2)2

Theodore A. Annan,   Rajesh Kumar  and  Dennis G. Tuck  

Abstract

The electrochemical oxidation of metal anodes in an acetonitrile solution of Ph2PH yields M(PPh2)(M = Cu, Ag, Au) or M(PPh2)2(M = Co, Zn, Cd); with a solution of Ph2PH and bis(diphenylphosphino)methane (dppm), this method gives Cu4(PPh2)4(dppm)2 whose structure is found to be very similar to that of Cu4(SC5H11)4(dppm)2.

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Article information

DOI
https://doi.org/10.1039/C39880000446
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 446-448

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The direct electrochemical synthesis of metal–diphenylphosphido complexes, and the crystal structure of Cu4(µ-PPh2)4(Ph2PCH2PPh2)2

T. A. Annan, R. Kumar and D. G. Tuck, J. Chem. Soc., Chem. Commun., 1988, 446 DOI: 10.1039/C39880000446

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