Issue 12, 1988

Oxidative cleavage of carbon–silicon bonds by dioxygen: catalysis by a flavin–dihydronicotinamide redox system

Abstract

Carbon–silicon bonds in alkoxy- or fluoro-silanes readily undergo cleavage by dioxygen (molecular oxygen), catalysed by tetra-acetylriboflavin (5–10 mol%) in the presence of N-benzyl-1,4-dihydronicotinamide as reductant, together with fluoride ions as an essential additive.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 795-797

Oxidative cleavage of carbon–silicon bonds by dioxygen: catalysis by a flavin–dihydronicotinamide redox system

K. Tamao, T. Hayashi and Y. Ito, J. Chem. Soc., Chem. Commun., 1988, 795 DOI: 10.1039/C39880000795

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