Issue 13, 1988

Synthesis of the unique 10π-electron 1,3,2-benzodithiaphospholium cation and a structural comparison with the phenyl phosphine derivative

Abstract

The first example of a dithiaphospholium cation is a 10π-electron planar heterocycle, which exhibits thermodynamically stable 3pπ–3pπ bonding between phosphorus and sulphur.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 842-844

Synthesis of the unique 10π-electron 1,3,2-benzodithiaphospholium cation and a structural comparison with the phenyl phosphine derivative

N. Burford, B. W. Royan, A. Linden and T. S. Cameron, J. Chem. Soc., Chem. Commun., 1988, 842 DOI: 10.1039/C39880000842

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