Olefinic methylenecyclopropanes undergo quantitative transannular ring closure under catalysis by Group 10 metals to give [3.3.3]propellanes, through cycloaddition of a trimethylenemethane-like intermediate.
S. Yamago and E. Nakamura, J. Chem. Soc., Chem. Commun., 1988, 1112 DOI: 10.1039/C39880001112
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