Upon reaction of 2,2-dimethylpropylidynephosphane with pentacarbonyl[2-aryl(methoxy)carbene]chromium complexes a regiospecific cycloaddition of phospha-alkyne, carbene, and carbonyl ligands leads to 1,3-oxaphospholes, the crystal structure of one example of which has been determined.
K. H. Dötz, A. Tiriliomis and K. Harms, J. Chem. Soc., Chem. Commun., 1989, 788 DOI: 10.1039/C39890000788
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