SCHEDULED MAINTENANCE
N-(Trimethylsilyl)amines direct ring-opening carbonylation of a variety of cyclic ethers such as oxiranes (1–3), oxetane (4), tetrahydrofuran (5), and 1,3-dioxolane (6) in the presence of a catalytic amount of Co2(CO)8 under carbon monoxide pressure to give siloxy amides.
Y. Tsuji, M. Kobayashi, F. Okuda and Y. Watanabe, J. Chem. Soc., Chem. Commun., 1989, 1253 DOI: 10.1039/C39890001253
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