Issue 20, 1989

Oxygen insertion by a new tyrosinase model binuclear CuI macrocyclic complex

Abstract

Benzene-1,3-dicarboxaldehyde and diethylenetriamine have been condensed to produce a new 24-atom tetra Schiff base binucleating macrocyclic ligand in good yield; the latter forms a dinuclear CuI complex which combines with dioxygen and inserts one of the oxygen atoms into the 2-position of the aromatic ring to form a phenolate- and hydroxide-bridged binuclear copper(II) complex.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1521-1523

Oxygen insertion by a new tyrosinase model binuclear CuI macrocyclic complex

R. Menif and A. E. Martell, J. Chem. Soc., Chem. Commun., 1989, 1521 DOI: 10.1039/C39890001521

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