Issue 21, 1989

Fast time-resolved IR studies of the excited states of co-ordination compound: direct observation of intramolecular charge transfer

Abstract

Fast time-resolved IR (TRIR) spectroscopy is used to record ν(C–O) bands of the lowest lying excited state of [ClRe(CO)3(4,4′-bipyridyl)2](half-life of approximately 1 µs in CH2Cl2 solution); there is a shift of the ν(C–O) bands to higher frequency relative to the ground state, which is consistent with oxidation of the metal centre via electron transfer to the bipyridyl ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1655-1657

Fast time-resolved IR studies of the excited states of co-ordination compound: direct observation of intramolecular charge transfer

P. Glyn, M. W. George, P. M. Hodges and J. J. Turner, J. Chem. Soc., Chem. Commun., 1989, 1655 DOI: 10.1039/C39890001655

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