Issue 22, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

A stable ruthenium(V) oxo complex. X-Ray crystal structure and oxidising properties of tetra-n-propylammonium bis-2-hydroxy-2-ethylbutyrato(oxo)-ruthenate(V)

Andrew C. Dengel,   William P. Griffith,   Caroline A. O'Mahoney  and  David J. Williams  

Abstract

The title complex, made from [Prn4N][RuO4] and 2-hydroxy-2-ethylbutyric acid, contains a distorted trigonal bipyramidal anion with a short Ru[double bond, length as m-dash]O equatorial bond (1.687 Å) and functions as a mild oxidant towards alcohols giving carbonyl compounds; such oxidations are catalytic with N-methylmorpholine N-oxide.

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Article information

DOI
https://doi.org/10.1039/C39890001720
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1720-1721

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A stable ruthenium(V) oxo complex. X-Ray crystal structure and oxidising properties of tetra-n-propylammonium bis-2-hydroxy-2-ethylbutyrato(oxo)-ruthenate(V)

A. C. Dengel, W. P. Griffith, C. A. O'Mahoney and D. J. Williams, J. Chem. Soc., Chem. Commun., 1989, 1720 DOI: 10.1039/C39890001720

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