Issue 22, 1989

X-Ray crystallographic and NMR evidence for a uniquely strong OH ⋯ N hydrogen bond in the solid state and solution

Abstract

Crystallographic and NMR evidence indicates that the neutral compound (1) has a strong and essentially linear [170(1)°] O–H ⋯ N intramolecular hydrogen bond as part of a seven membered ring, with uniquely short O ⋯ N and H ⋯ N distances of 2.465(5) and 1.32(2)Å and an O–H distance of 1.16(2)Å respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1722-1723

X-Ray crystallographic and NMR evidence for a uniquely strong OH ⋯ N hydrogen bond in the solid state and solution

P. Camilleri, C. A. Marby, B. Odell, H. S. Rzepa, R. N. Sheppard, J. J. P. Stewart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1989, 1722 DOI: 10.1039/C39890001722

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements