Issue 24, 1989

Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

Abstract

UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the µ-dinitrogen complex has been determined and the Os–N(N2) distances found to be 1.873(9) and 1.893(9)Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1883-1884

Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [OsVI(NH3)4N]3+

C. Che, H. Lam, W. Tong, T. Lai and T. Lau, J. Chem. Soc., Chem. Commun., 1989, 1883 DOI: 10.1039/C39890001883

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