SCHEDULED MAINTENANCE
Multinuclear variable temperature NMR studies on [MCl{N(SiMe2CH2PMe2)2}2], M = La or Lu, and [LuPh{N(SiMe2CH2PMe2)2}2] conclusively show phosphine co-ordination to these hard metal centres; in the case of lanthanum, this is the first reported phosphine complex.
M. D. Fryzuk and T. S. Haddad, J. Chem. Soc., Chem. Commun., 1990, 1088 DOI: 10.1039/C39900001088
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