SCHEDULED MAINTENANCE
The sterically crowded cis-[Ru(dmp)2S2](PF6)2(dmp = 2,9 dirnethyl-1,10-phenanthroline, S = Me3CN or H2O) is capable of hydroxylating methane under mild reaction conditions utilizing H2O2 as the primary oxidant; oxidation of this complex with H2O2 is studied spectrophotometrically by UV–VIS and NMR spectroscopy implicating ruthenium(VI) as the active oxidant.
A. S. Goldstein and R. S. Drago, J. Chem. Soc., Chem. Commun., 1991, 21 DOI: 10.1039/C39910000021
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