Issue 5, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Reactions of catecholatoborane with phosphinorhodium complexes: molecular structures of [RhHCl(Bcat)(PPri3)2] and [{(Pri2PCH2)2}Rh{(η6-cat)Bcat}](cat = 1,2-O2C6H4)

Stephen A. Westcott,   Nicholas J. Taylor,   Todd B. Marder,   R. Thomas Baker,   Nancy J. Jones  and  Joseph C. Calabrese  

Abstract

Addition of catecholatoborane (HBcat), 1, to [RhCl(N2)(PPri3)2] gives the first structurally characterised, unsaturated boryl complex, [RhHCl(Bcat)(PPri3)2], whereas reaction of [{(Pri2PCH2)2}Rh(η3-2-Me-allyl)] with 2 equiv. of 1 affords [{(Pri2PCH2)2Rh{(η6-cat)Bcat}]via B-substituent redistribution; both complexes catalyse the hydroboration of oct-1-ene with 1

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Article information

DOI
https://doi.org/10.1039/C39910000304
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 304-305

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Reactions of catecholatoborane with phosphinorhodium complexes: molecular structures of [RhHCl(Bcat)(PPri3)2] and [{(Pri2PCH2)2}Rh{(η6-cat)Bcat}](cat = 1,2-O2C6H4)

S. A. Westcott, N. J. Taylor, T. B. Marder, R. T. Baker, N. J. Jones and J. C. Calabrese, J. Chem. Soc., Chem. Commun., 1991, 304 DOI: 10.1039/C39910000304

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