Selective cross-disproportion between vinylsilanes and various mono-substituted alkenes is catalysed by [RuCl(CO)H(PPh3)3]1; the mechanism of this reaction has been elucidated based on reactions of 1 with vinylsilanes as well as those of the resulting ruthenium–silyl complex with alkenes.
Y. Wakatsuki, H. Yamazaki, M. Nakano and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1991, 703 DOI: 10.1039/C39910000703
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