The reaction of VOCl3 with bulky biphenolic compounds (H2L) provides dark brown complexes of formula, [V(O)(L)Cl]; X-ray diffraction studies revealed that the complex for which L = 2,2′-CH2(4-Me,6-ButC6H2O)2 is monomeric in the solid state with approximate tetrahedral geometry about the V atom.
P. J. Toscano, E. J. Schermerhorn, C. Dettelbacher, D. Macherone and J. Zubieta, J. Chem. Soc., Chem. Commun., 1991, 933 DOI: 10.1039/C39910000933
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