SCHEDULED MAINTENANCE
A transient radical cation with an intramolecular sulphur–phosphorus 2σ–1σ* three-electron bond is generated during the oxidation of 1-(diethylphosphino)-3-(methylthio)propane 1 in aqueous solution; it shows an optical absorption at λmax= 385 nm.
H. Hungerbühler, S. N. Guha and K. Asmus, J. Chem. Soc., Chem. Commun., 1991, 999 DOI: 10.1039/C39910000999
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