Issue 6, 1992

Synthesis and X-ray crystal structure of [Eu(η6-C6Me6)(AlCl4)2]4; the first cyclotetrameric lanthanide(II) complex with a neutral π-ligand

Abstract

The reaction of EuCl3, AlCl3 and C6Me6 in toluene gives the EuII complex [Eu(η6-C6Me6)(AlCl4)2]4; X-ray crystal determination shows the molecule to be a cyclotetramer, in which the four Eu(C6Me6)AlCl4 units are connected via four groups of η2-AlCl4.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 480-481

Synthesis and X-ray crystal structure of [Eu(η6-C6Me6)(AlCl4)2]4; the first cyclotetrameric lanthanide(II) complex with a neutral π-ligand

H. Liang, Q. Shen, S. Jin and Y. Lin, J. Chem. Soc., Chem. Commun., 1992, 480 DOI: 10.1039/C39920000480

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