Formic acid, isolable as sodium formate from the reaction mixture, is produced directly from hydrogen and carbon dioxide with yields up to 1150 moles per mole of rhodium using a homogeneous catalyst formed in situ from [{Rh(cod)Cl}2] and Ph2P(CH2)4PPh2; the precious metal is recovered during work-up in a catalytically active form.
E. Graf and W. Leitner, J. Chem. Soc., Chem. Commun., 1992, 623 DOI: 10.1039/C39920000623
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