Issue 22, 1992

c-Arylglycosylation of unprotected free sugar

Abstract

Highly regio- and stereo-selective C-arylglycosylations of the protected free sugars 14, the unprotected methyl glycosides 69 and the unprotected free sugars 10 and 11 with 2-naphthol 5 are effectively realized by the combined use of TMSOTf–AgClO4(TMSOTf = trimethylsilyloxytrifluoromethanesulfonate) as a catalytic activator.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1641-1642

c-Arylglycosylation of unprotected free sugar

K. Toshima, G. Matsuo, T. Ishizuka, M. Nakata and M. Kinoshita, J. Chem. Soc., Chem. Commun., 1992, 1641 DOI: 10.1039/C39920001641

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