Reaction of UCl4 with the potassium salt of the tetramethylphospholyl anion afforded the title compound, which has been transformed into the derivatives [U(η-C4Me4P)3X](X = H, Me, OPri); the trigonal crystal structure revealed that the three phospholyl ligands are pentahapto bonded to the uranium.
P. Gradoz, C. Boisson, D. Baudry, M. Lance, M. Nierlich, J. Vigner and M. Ephritikhine, J. Chem. Soc., Chem. Commun., 1992, 1720 DOI: 10.1039/C39920001720
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