Issue 2, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and crystal and molecular structure of (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,III mixed-valence cluster with the decametallate core geometry

Michael Cavaluzzo,   Qin Chen  and  Jon Zubieta  

Abstract

The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.

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Article information

DOI
https://doi.org/10.1039/C39930000131
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 131-133

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Synthesis and crystal and molecular structure of (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,III mixed-valence cluster with the decametallate core geometry

M. Cavaluzzo, Q. Chen and J. Zubieta, J. Chem. Soc., Chem. Commun., 1993, 131 DOI: 10.1039/C39930000131

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