Various organoiron(II) reagents undergo Grignard-type additions to substituted cyclohexanone derivatives, C–C bond formation occurring stereoselectively from the equatorial direction (97–100% selectivity).
M. T. Reetz and S. Stanchev, J. Chem. Soc., Chem. Commun., 1993, 328 DOI: 10.1039/C39930000328
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