The relative and absolute configuration of Stigmatellin A, isolated from the myxobacterium Stigmatella aurantiaca and a powerful inhibitor of electron transport, is determined through chemical correlation by employing a combination of our SAMP/RAMP hydrazone method and the Evans syn-aldol protocols.
D. Enders and S. Osborne, J. Chem. Soc., Chem. Commun., 1993, 424 DOI: 10.1039/C39930000424
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