Issue 8, 1993

First photosensitized enantiodifferentiating polar addition: anti-markovnikov methanol addition to 1,1-diphenylpropene

Abstract

Enantiodifferentiating methanol addition to 1,1-diphenylpropene sensitized by chiral naphthalene(di)carboxylates gave optically active 1,1-diphenyl-2-methoxypropane in optical yields up to 27%, indicating the intervention of an intimately interacting exciplex or contact ion pair.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 718-720

First photosensitized enantiodifferentiating polar addition: anti-markovnikov methanol addition to 1,1-diphenylpropene

Y. Inoue, T. Okano, N. Yamasaki and A. Tai, J. Chem. Soc., Chem. Commun., 1993, 718 DOI: 10.1039/C39930000718

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