A zerovalent iron dinitrogen complex [Fe(N2)(depe)2] having 1,2-bis(diethylphosphino)ethane ligands has been prepared by reduction of [FeCl2(depe)2] with sodium–naphthalene in tetrahydrofuran under nitrogen at room temperature.
S. Komiya, M. Akita, A. Yoza, N. Kasuga, A. Fukuoka and Y. Kai, J. Chem. Soc., Chem. Commun., 1993, 787 DOI: 10.1039/C39930000787
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