SCHEDULED MAINTENANCE
Ruthenium 5,10,15,20-tetramesitylporphyrin, Ru(tmp), reacts with 1 equiv. of N2CHCO2Et to afford the ethoxycarbonylcarbene [Ru(tmp)![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CHCO2Et] in the presence of an excess of N2CHCO2Et; the latter catalyses the formation of diethyl maleate as the major product at a rate of approximately one turnover per second.
J. P. Collman, E. Rose and G. D. Venburg, J. Chem. Soc., Chem. Commun., 1993, 934 DOI: 10.1039/C39930000934
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