Issue 7, 1994

Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH4)2(OC4H8)5][(BH4)3U(µ-η77-C7H7)U(BH4)3]

Abstract

The anions [X3U(µ-η77-C7H7)UX3](X = NEt2 or BH4) have been obtained by treatment of UX4 with K[C7H9]; the cation [U(BH4)2(thf)5]+ was formed by protonation of [U(BH4)3(thf)3] with [NHEt3][BPh4] in tetrahydrofuran (thf).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 847-848

Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH4)2(OC4H8)5][(BH4)3U(µ-η77-C7H7)U(BH4)3]

T. Arliguie, M. Lance, M. Nierlich, J. Vigner and M. Ephritikhine, J. Chem. Soc., Chem. Commun., 1994, 847 DOI: 10.1039/C39940000847

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