Issue 9, 1994

A novel cis-dioxoruthenium(VI) complex of N,N′,N″-trimethyl-1,4,7-triazacyclononane (Me3tacn) for organic oxidation

Abstract

The X-ray structure of [Ru(Me3tacn)O2(CF3CO2)]+ shows a cis-dioxoruthenium(VI) unit with the Ru[double bond, length half m-dash]O distances and O–Ru–O angle being 1.717(9) and 1.715(9)Å and 118.3(4)° respectively, this RuVI complex catalyses alkene epoxidation and alkane hydroxylation by PhIO and ButOOH.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1063-1064

A novel cis-dioxoruthenium(VI) complex of N,N′,N″-trimethyl-1,4,7-triazacyclononane (Me3tacn) for organic oxidation

W. Cheng, W. Yu, K. Cheung and C. Che, J. Chem. Soc., Chem. Commun., 1994, 1063 DOI: 10.1039/C39940001063

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