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Incubations of (4R)- and (4S)-[4-2H1]-proclavaminic acid with clavaminic acid synthase resulted in the stereospecific removal of the deuterium and hydrogen respectively from C-4, in their conversions to clavaminic acid, suggesting an enzyme catalysed syn-eliminaion for the desaturation of dihydroclavaminic acid to clavaminic acid.
J. E. Baldwin, R. M. Adlington, N. P. Crouch, D. J. Drake, Y. Fujishima, S. W. Elson and K. H. Baggaley, J. Chem. Soc., Chem. Commun., 1994, 1133 DOI: 10.1039/C39940001133
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