A magneto-structural relationship showing linear dependence of antiferromagnetic exchange coupling constant (–J) on Ni–O–Ni bridge angle as well as the intramolecular Ni ⋯ Ni distance has been obtained with a series of phenoxy-bridged macrocyclic dinickel(II) complexes with centrosymmetric structures.
K. K. Nanda, L. K. Thompson, J. N. Bridson and K. Nag, J. Chem. Soc., Chem. Commun., 1994, 1337 DOI: 10.1039/C39940001337
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