Issue 12, 1994

The kinetic range of carbene–pyridine ylide forming reactions

Abstract

Absolute rate constants for the ylide-forming reactions of 16 carbenes with pyridine range from 1.4 × 1010 to 1.2 × 105 dm3 mol–1 s–1, and can be rationalized by frontier molecular orbital theory.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1479-1480

The kinetic range of carbene–pyridine ylide forming reactions

C. Ge, E. G. Jang, E. A. Jefferson, W. Liu, R. A. Moss, J. Włostowska and S. Xue, J. Chem. Soc., Chem. Commun., 1994, 1479 DOI: 10.1039/C39940001479

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