Issue 16, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Transfer dehydrogenative coupling of triethylsilane catalysed by ruthenium and rhodium complexes. A new Si–C bond forming process

Peter I. Djurovich,   Alfred R. Dolich  and  Donald H. Berry  

Abstract

Four-legged piano stool complexes (η6-arene)Ru(H)2(SiEt3)2 and (η5-C5Me5)Rh(H)2(SiEt3)2 catalyse the transfer dehydrogenative coupling of Et3SiH in the presence of a hydrogen acceptor such as tert-butylethylene to yield the carbosilane dimer, HSiEt2CHMeSiEt3, and 2,2-dimethylbutane by a mechanism involving an intermediate η2-silene complex, LnM(Et2Si[double bond, length half m-dash]CHMe), generated by β-hydrogen elimination from a silyl group.

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Article information

DOI
https://doi.org/10.1039/C39940001897
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1897-1898

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Transfer dehydrogenative coupling of triethylsilane catalysed by ruthenium and rhodium complexes. A new Si–C bond forming process

P. I. Djurovich, A. R. Dolich and D. H. Berry, J. Chem. Soc., Chem. Commun., 1994, 1897 DOI: 10.1039/C39940001897

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