Issue 16, 1994

Allylic sulfones as allyl anion equivalents: homoallylic alcohols from metal catalysed reactions of sulfones with aldehydes and ketones

Abstract

Reduction of allylic sulfones with diethylzinc, catalysed by palladium(0), gives nucleophilic organometallic species, which react in situ with carbonyl compounds to give homoallylic alcohols in high yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1905-1906

Allylic sulfones as allyl anion equivalents: homoallylic alcohols from metal catalysed reactions of sulfones with aldehydes and ketones

J. Clayden and M. Julia, J. Chem. Soc., Chem. Commun., 1994, 1905 DOI: 10.1039/C39940001905

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