Issue 17, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of a new binucleating ligand LH4: synthesis and X-ray structures of anti-[Co2(LH4)(OH2)2](NO3)4·5H2O, anti-[Ni2(LH4)(NCMe)2](PF6)4·4H2O, anti-[Zn2(LH4)(NO3)2](NO3)2 and syn-[Cu2(LH2)](BPh4)2

Alexander J. Blake,   Therese M. Donlevy,   Paul A. England,   Ian A. Fallis,   Simon Parsons,   Steven A. Ross  and  Martin Schröder  

Abstract

The binuclear octahedral MII complexes [Co2(LH4)(H2O)2]4+, [Ni2(LH4)(NCMe)2]4+ and [Zn2(LH4)(NO3)2]2+, incorporating the new 10 coordinate pendant arm ligand LH4, all show an anti-configuration; in contrast the CuII complex [Cu2(LH2)]2+ adopts a syn-configuration incorporating intramolecular H-bonding.

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Article information

DOI
https://doi.org/10.1039/C39940001981
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1981-1982

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Synthesis of a new binucleating ligand LH4: synthesis and X-ray structures of anti-[Co2(LH4)(OH2)2](NO3)4·5H2O, anti-[Ni2(LH4)(NCMe)2](PF6)4·4H2O, anti-[Zn2(LH4)(NO3)2](NO3)2 and syn-[Cu2(LH2)](BPh4)2

A. J. Blake, T. M. Donlevy, P. A. England, I. A. Fallis, S. Parsons, S. A. Ross and M. Schröder, J. Chem. Soc., Chem. Commun., 1994, 1981 DOI: 10.1039/C39940001981

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