Issue 21, 1994

Allyl, amidinium and cyclopropenyl cations from the reactions of primary and secondary amines with pentachlorocyclopropane

Abstract

The action of secondary amines on c–C3HCl5 is a simple new route to aminocyclopropenyl ions, whereas primary amines cause ring opening to an allyl cation, e.g.[(ButHN)2CCHC(NHBut)2]+ identified crystallographically, which is reversibly protonated at the central carbon to become a bis(amidinium) dication.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2517-2518

Allyl, amidinium and cyclopropenyl cations from the reactions of primary and secondary amines with pentachlorocyclopropane

M. J. Taylor, P. W. J. Surman and G. R. Clark, J. Chem. Soc., Chem. Commun., 1994, 2517 DOI: 10.1039/C39940002517

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