Reaction of (1-naphthyl)phenylsilane with symmetric aliphatic ketones catalysed by (R)-Cybinap–RhI gave the corresponding (R)-(alkoxy)(1-naphthyl)phenylsilane in >99% enantiomeric excess.
T. Ohta, M. Ito, A. Tsuneto and H. Takaya, J. Chem. Soc., Chem. Commun., 1994, 2525 DOI: 10.1039/C39940002525
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