Issue 23, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthtesis and reactivity of new chalcogen-rich aqua ions [Mo3S7(H2O)6]4+ and [Mo3Se7(H2O)6]4+

Vladimir P. Fedin,   Gert J. Lamprecht  and  A. Geoffrey Sykes  

Abstract

The aqua ions [Mo3Y7(H2O)6]4+(Y = S, Se) containing µ3-Y and µ-Y2 core ligands have been prepared for the first-time, enabling chalcogen-transfer reactions with an H2O-soluble phosphine to generate the well-characterised [Mo3Y4(H2)O9]4+, reaction with Cl- to give substitution of H2O ligands (which are of two different types), and heterometallic SnII addition reactions to be studied.

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Article information

DOI
https://doi.org/10.1039/C39940002685
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2685-2686

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Synthtesis and reactivity of new chalcogen-rich aqua ions [Mo3S7(H2O)6]4+ and [Mo3Se7(H2O)6]4+

V. P. Fedin, G. J. Lamprecht and A. G. Sykes, J. Chem. Soc., Chem. Commun., 1994, 2685 DOI: 10.1039/C39940002685

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