The new tripodal ligand tris-[3-(2′-pyridyl)pyrazol-1-yl]hydroborate (L–), comprising three N,N-bidentate chelating arms linked by the apical boron atom, has been synthesized; the crystal structure of [EuL(MeOH)2F][PF6] reveals the nine-coordinate metal lying within the hexadentate ligand cavity.
A. J. Amoroso, A. M. C. Thompson, J. C. Jeffery, P. L. Jones, J. A. McCleverty and M. D. Ward, J. Chem. Soc., Chem. Commun., 1994, 2751 DOI: 10.1039/C39940002751
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