Issue 3, 1995

The structure of W(CO)5L (L = pyridine, piperidine) in the lowest ligand field excited state determined by fast time-resolved IR spectroscopy; unexpected C–O bond length changes

Abstract

The frequencies of the ν(CO) bands of W(CO)5L (L = pyridine and piperidine) in the lowest ligand field (LF) excited states have been obtained by fast time-resolved IR spectroscopy of the species dissolved in low-temperature glasses, and the shifts from the ground state indicate that the C–O bonds lengthen on excitation, contrary to the interpretation of the pre-resonance Raman spectroscopy on the ground state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 391-393

The structure of W(CO)5L (L = pyridine, piperidine) in the lowest ligand field excited state determined by fast time-resolved IR spectroscopy; unexpected C–O bond length changes

F. P. A. Johnson, M. W. George, S. L. Morrison and J. J. Turner, J. Chem. Soc., Chem. Commun., 1995, 391 DOI: 10.1039/C39950000391

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