The reversible insertion of the vinylsilane molecule into the Ru–Si bond occurs in two different ways to give E-1,2-bis(silyl)ethene and 1,1-bis(silyl)ethene which, in combination with the previous experiments by Wakatsuki et al., provides convincing evidence for a non-metallacarbene mechanism of silylalkene disproportionation.
B. Marciniec and C. Pietraszuk, J. Chem. Soc., Chem. Commun., 1995, 2003 DOI: 10.1039/C39950002003
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