Borate-substituted di- and tri-anionic cyclopentadienyi ligands [X3B–C5H4]2– and [X2B(C5H4)2]3–-(X = C6F5) give anionic group 4 metallocene complexes which provide a facile route to zwitterionic ‘single-component’ alkene polymerisation catalysts.
M. Bochmann, S. J. Lancaster and O. B. Robinson, J. Chem. Soc., Chem. Commun., 1995, 2081 DOI: 10.1039/C39950002081
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